Analytical Developments in Secondary Ion Mass Spectrometry 2003     

Etienne Deloule  Michael Wiedenbeck 《Geostandards and Geoanalytical Research》2005,29(1):37-40

This annual review of secondary ion mass spectrometry (SIMS) highlights significant progress in the application of the technology for the following areas: U-Pb geochronology (notably in the fields of reference material zircons), sources of uncertainty during analysis and secondary ion yields. Major publications introduced a new zircon reference sample and dealt with an intercomparison study of a suite of established calibrators, some of which have been shown to have certain limitations. Another publication claimed that the principal uncertainty in U-Pb dating is related to variations in the Pb and U relative emission yields over a complete analytical session. 2003 saw the introduction of an automated particle identification procedure applied to the analysis of a chondritic meteorite, as well as new geometries of SIMS hardware (NanoSIMS) and techniques (time-of-flight SIMS). NanoSIMS allows a two to three order of magnitude reduction in sampling volume as a result of a reduced beam diameter, and time-of-flight SIMS allows the study of sample surfaces, and can provide data for elements concurrently.  相似文献   

Mdantsane,East London's homeland township: Municipal neglect and apartheid planning 1949–1988     

Nel Etienne Louis 《GeoJournal》1990,22(3):305-313

South African urban areas, because of structural control exercised within them, have developed unique characteristics. One of the more distinctive features of urban apartheid is the creation of Homeland townships lying adjacent to certain of the country's towns and cities. This paper seeks to explore the essential motivation underlying the creation of the ethnically distinct urban centre of Mdantsane in the Ciskei Homeland between 1949 and 1988. The reason for the development of Mdantsane, a dormitory township of East London, are explored, as are the primary issues underlying its emergence. In order to fully investigate Mdantsane's evolution it is essential not to divorce the township from developments, through time, in East London. The impact of apartheid planning on the East London region is assessed.  相似文献   

Water penetration through fractured rocks: Test of a tridimensional percolation description     

Stephan Wilke  Etienne Guyon  Ghislain de Marsily 《Mathematical Geosciences》1985,17(1):17-27

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Development of a high resolution runoff routing model, calibration and application to assess runoff from the LMD GCM   总被引：3，自引：0，他引：3  

Agns Ducharne  Catherine Golaz  Etienne Leblois  Katia Laval  Jan Polcher  Emmanuel Ledoux  Ghislain de Marsily 《Journal of Hydrology》2003,280(1-4):207-228

Large-scale runoff routing models (RRMs) are important as a validation tool for GCMs, and to close the hydrological cycle in fully-coupled climate models. The model RiTHM was developed to simulate the discharge of large rivers from the total runoff simulated by the LMD GCM. It uses a 1024×800 grid, nested in the 64×50 grid of the LMD GCM. The runoff simulated in a GCM grid cell is uniformly distributed over the underlying cells, where a series of two reservoirs accounts for the delay related to infiltration through the unsaturated zone and aquifers. The resulting riverflow is routed assuming pure translation along the drainage network, extracted with a GIS from a 5 min DEM. The transfer time from a cell to the outlet depends on topography, and on a basin-wide parameter, the time of concentration. RiTHM was calibrated in 11 river basins, using a realistic runoff forcing (computed by the land surface model SECHIBA from reanalyzed meteorological forcing). This led to a very satisfactory reproduction of observed hydrographs. The main problems were related to hydraulic processes neglected in RiTHM (reservoirs, diversion of riverflow because of flooding or irrigation). These results helped to validate SECHIBA, except for its snow processes, shown to be too simple. With the same parameters, RiTHM was also forced with runoff from the LMD GCM. This induced an important degradation of the simulated hydrographs, regarding both volume and timing. It was largely explained by errors in precipitation, and more generally climate, in the GCM. The direct calibration of RiTHM under the GCM-runoff forcing markedly improved the timing of simulated discharge, which could be interesting for land–atmosphere–ocean coupling. This work demonstrated that the usefulness of RRMs for GCMs strongly depends on their adequate calibration.  相似文献   

V oxidation state in Fe–Ti oxides by high-energy resolution fluorescence-detected X-ray absorption spectroscopy     

Amélie Bordage  Etienne Balan  Johan P. R. de Villiers  Robert Cromarty  Amélie Juhin  Claire Carvallo  Georges Calas  P. V. Sunder Raju  Pieter Glatzel 《Physics and Chemistry of Minerals》2011,38(6):449-458

The oxidation state of vanadium in natural and synthetic Fe–Ti oxides is determined using high-energy resolution fluorescence-detected X-ray absorption spectroscopy (HERFD-XAS). Eleven natural magnetite-bearing samples from a borehole of the Main Magnetite Layer of the Bushveld Complex (South Africa), five synthetic Fe oxide samples, and three natural hematite-bearing samples from Dharwar supergroup (India) are investigated. V K edge spectra were recorded on the ID26 beamline at the European Synchrotron Radiation Facility (Grenoble, France), and the pre-edge features were used to determine the local environment and oxidation state of vanadium. In the case of the magnetite samples (natural and synthetic), we show that vanadium is incorporated in the octahedral site of the spinel structure under two oxidation states: +III and +IV. The variations of the pre-edge area are interpreted as various proportions in V³⁺ and V⁴⁺ (between 9.5 and 16.3% of V⁴⁺), V³⁺ being the main oxidation state. In particular, the variations of the V⁴⁺/V³⁺ ratio along the profile of the Main Magnetite Layer seem to follow the crystallization sequence of the layer. In the case of the hematite samples from India, the pre-edge features indicate that vanadium is substituted to Fe and mainly incorporated as V⁴⁺ (between 40 and 72% of V⁴⁺). We also demonstrate the potentiality of HERFD-XAS for mineralogical studies, since it can filter out the unwanted fluorescence and give better resolved spectra than conventional XAS.  相似文献   

“Stones from the dangerous winds”: reef platform mega-clasts in the tropical Pacific Islands     

James P. Terry  Samuel Etienne 《Natural Hazards》2011,56(3):567-569

Tsunamis and intense tropical storms compete as viable mechanisms for catastrophic marine inundations of coastlines, and so interpretation of deposits laid down by palaeo-events is often problematic. Here, examples are presented from the tropical South Pacific Islands to demonstrate how indigenous knowledge may provide vital clues supporting sedimentological investigation and thereby helping to explain the origin of giant boulders emplaced on top of coral reef platforms.  相似文献   

Deciphering the weathering processes using environmental mineralogy and geochemistry: Towards an integrated model of laterite and podzol genesis in the Upper Amazon Basin     

Emmanuel Fritsch  Etienne Balan  Nadia Régina Do Nascimento  Thierry Allard  Marion Bardy  Guilherme Bueno  Sylvie Derenne  Adolpho José Melfi  Georges Calas 《Comptes Rendus Geoscience》2011,343(2-3):188-198

This article reports major results from collaborative research between France and Brazil on soil and water systems, carried out in the Upper Amazon Basin. It reveals the weathering processes acting in the partly inundated, low elevation plateaus of the Basin, mostly covered by evergreen forest. Our findings are based on geochemical data and mineral spectroscopy that probe the crystal chemistry of Fe and Al in mineral phases (mainly kaolinite, Al- and Fe-(hydr)oxides) of tropical soils (laterites). These techniques reveal crystal alterations in mineral populations of different ages and changes of metal speciation associated with mineral or organic phases. These results provide an integrated model of soil formation and changes (from laterites to podzols) in distinct hydrological compartments of the Amazon landscapes and under altered water regimes.  相似文献   

F and G Taylor series solutions to the Stark and Kepler problems with Sundman transformations     

Etienne Pellegrini  Ryan P. Russell  Vivek Vittaldev 《Celestial Mechanics and Dynamical Astronomy》2014,118(4):355-378

The classic $F$ and $G$ Taylor series of Keplerian motion are extended to solve the Stark problem and to use the generalized Sundman transformation. Exact recursion formulas for the series coefficients are derived, and the method is implemented to high order via a symbolic manipulator. The results lead to fast and accurate propagation models with efficient discretizations. The new $F$ and $G$ Stark series solutions are compared to the Modern Taylor Series (MTS) and 8th order Runge–Kutta–Fehlberg (RKF8) solutions. In terms of runtime, the $F$ and $G$ approach is shown to compare favorably to the MTS method up to order 20, and both Taylor series methods enjoy approximate order of magnitude speedups compared to RKF8 implementations. Actual runtime is shown to vary with eccentricity, perturbation size, prescribed accuracy, and the Sundman power law. The method and results are valid for both the Stark and the Kepler problems. The effects of the generalized Sundman transformation on the accuracy of the propagation are analyzed. The Taylor series solutions are shown to be exceptionally efficient when the unity power law from the classic Sundman transformation is applied. An example low-thrust trajectory propagation demonstrates the utility of the $F$ and $G$ Stark series solutions.  相似文献   

Editorial     

Eric Pawson  Etienne Nel 《New Zealand geographer》2011,67(1):1-1

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Uraniferous bitumen nodules in the Talvivaara Ni–Zn–Cu–Co deposit (Finland): influence of metamorphism on uranium mineralization in black shales     

Andreï Lecomte  Michel Cathelineau  Etienne Deloule  Marc Brouand  Chantal Peiffert  Kirsti Loukola-Ruskeeniemi  Esa Pohjolainen  Hannu Lahtinen 《Mineralium Deposita》2014,49(4):513-533

In the central part of the Fennoscandian Shield, the Talvivaara Ni–Zn–Cu–Co deposit, hosted by Palaeoproterozoic metamorphosed black schists, contains low uranium concentrations ranging from 10 to 30 ppm. The Talvivaara black schists were deposited 2.0–1.9 Ga ago and underwent subsequent metamorphism during the 1.9–1.79 Ga Svecofennian orogeny. Anhedral uraninite crystals rimmed by bitumen constitute the main host of uranium. U–Pb secondary ion mass spectrometry dating indicates that uraninite crystals were formed between 1,878?±?17 and 1,871?±?43 Ma, during peak metamorphism. Rare earth element patterns and high Th content (average 6.38 wt%) in disseminated uraninite crystals indicate that U was concentrated during high temperature metamorphism (>400 °C). The formation of bitumen rims around uraninite may be explained by two distinct scenarios: (a) a transport of U coincident with the migration of hydrocarbons or (b) post-metamorphic formation of bitumen rims, through radiolytic polymerization of gaseous hydrocarbons at the contact with uraninite.  相似文献